Total Synthesis Of Pleosporol A And Its Stereoisomers

TETRAHEDRON（2021）

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摘要

The cyclohexenone derivatives pleosporols A, B and stemfolone B were reported as novel antibacterial agents. In this study, we reported the first total synthesis of pleosporol A and its stereoisomers from arabinose, utilizing intramolecular nitrone-alkene cycloaddition and Hofmann elimination under Swern condition for constructing the cyclohexene ring. (C) 2020 Elsevier Ltd. All rights reserved.

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关键词

Pleosporol, Antimicrobial, Cycloaddition, Total synthesis, Enantiomers

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