Observation of gerade Rydberg state of Cd2 van der Waals complex cooled in free-jet expansion beam and excited using optical-optical double resonance method

Tomasz Urbańczyk,Marek Krośnicki,Jarosław Koperski

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY（2021）

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摘要

•Observation of gerade Rydberg electronic energy state of Cd2.•The gerade Rydberg state excited using OODR method.•Ab initio calculated 31g(63S1) - state interatomic potential.•Analysis of vibrational progression and isotopic structure.

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关键词

Cadmium van der Waals complex,gerade Rydberg electronic state,Interatomic potential,Free-jet expansion beam,Optical-optical double resonance

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