Olefin epoxidation with ionic liquid catalysts formed by supramolecular interactions

Bingjie Ding,Ran Zhang,Qingqing Zhou,Wenbao Ma,Anna Zheng,Difan Li,Yefeng Yao,Zhenshan Hou

Molecular Catalysis（2021）

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摘要

•The supramolecular ILs consisted of 18-crown-6 and ammonium peroxoniobate.•The IL have been constructed via non-covalent interaction.•The IL showed the excellent catalytic activity, selectivity and recyclability.•The interconversion of NbO and active niobium-peroxo species was reversible.•The supramolecular complexation can enhance the activity for epoxidation.

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关键词

Ionic liquid,Peroxoniobate,Crown ether,Supramolecularinteraction,Olefin epoxidation

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