Liquid-liquid equilibrium measurements and interaction explorations for separation of azeotrope n-butyl acetate and n-butanol using three ionic liquids

Dan Wang,Feng Wei,Juan A. Reyes-Labarta,Zhaojie Wang,Dongmei Xu,Jun Gao,Lianzheng Zhang,Yinglong Wang

The Journal of Chemical Thermodynamics（2021）

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摘要

•Three ionic liquids were adopted to separate the azeotrope NBAC and NBA.•The LLE data for NBAC + NBA + ILs were measured and correlated by the NRTL model.•The interaction was explored by hydrogen bond length and interaction energy.•The influence of the carbon chain length of cations on phase behavior was explored.

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关键词

Liquid-liquid equilibrium,Extraction,n-Butanol,n-Butyl acetate,Ionic liquids

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