Two dinuclear GdIII clusters based on isobutyric acid and nicotinic acid with large magnetocaloric effects
Journal of Molecular Structure(2021)
摘要
•Two dinuclear GdIII clusters based on two light monocarboxylate ligands have been hydrothermally prepared and structurally characterized.•The carboxylate groups take different coordination modes.•They exhibit ferromagnetic behaviors with large magnetocaloric effects.
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关键词
Dinuclear GdIII clusters,Monocarboxylate ligands,Hydrothermal reaction,Ferromagnetic interactions,Magnetocaloric effect,Magnetic entropy changes
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