Two dinuclear GdIII clusters based on isobutyric acid and nicotinic acid with large magnetocaloric effects

Journal of Molecular Structure(2021)

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摘要
•Two dinuclear GdIII clusters based on two light monocarboxylate ligands have been hydrothermally prepared and structurally characterized.•The carboxylate groups take different coordination modes.•They exhibit ferromagnetic behaviors with large magnetocaloric effects.
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关键词
Dinuclear GdIII clusters,Monocarboxylate ligands,Hydrothermal reaction,Ferromagnetic interactions,Magnetocaloric effect,Magnetic entropy changes
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