Integrating Molecular Rigidity And Chirality Into Thermally Activated Delayed Fluorescence Emitters For Highly Efficient Sky-Blue And Orange Circularly Polarized Electroluminescence

By integrating high molecular rigidity and stable chirality, two pairs of D*-A type circularly polarized thermally activated delayed fluorescence (CP-TADF) emitters with an almost absolute quasi-equatorial conformer geometry and excellent photoluminescence quantum efficiencies (PLQYs) are developed, achieving state-of-the-art electroluminescence performance among blue and orange circularly polarized organic light-emitting diodes (CP-OLEDs).