Electronic and molecular characterization of an air-stable Cr(II) complex containing azo-anion-radicals

Debojyoti Mukherjee,Rabindra Nath Manna,Paramita Saha,Ujjwal Mandal,Mainak Mitra

Journal of Molecular Structure（2021）

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摘要

•An octahedral low-spin Cr(II) complex containing delocalized azo-anion-radical ligands is reported.•Electron transfer from metal center to ligand center is the key in the formation of Cr(II) complex from its low-valent precursor compound.•DFT study provides mechanistic support of the redox process and the attainment of low-spin state in Cr(II) center.

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关键词

Redox-active,Chromium,Pincer ligand,Azo-anion-radical

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