Polypropylene-Grafted Poly(Hexamethylene Guanidine)/Modified Polyethylene Monofilament And Its Antimicrobial Performance

INTERNATIONAL JOURNAL OF POLYMER SCIENCE(2020)

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摘要
A polypropylene-grafted poly(hexamethylene guanidine) (PP-g-PHMG)/polyethylene (PE) monofilament was prepared by melt blending and spinning using PE and PP-g-PHMG. The effect of PP-g-PHMG content on the structure, mechanical properties, and antimicrobial properties of PP-g-PHMG/PE alloy monofilaments was studied. Compared with PP/PE without grafting PHMG,Tmof PP-g-PHMG/PE alloy monofilaments increased due to rigidity of PHMG grafted. In the PP-g-PHMG/PE alloy monofilaments, the total degree of crystallinity of alloy monofilaments decreased; hence, the alpha-relaxation associated with the crystalline region of the polymer matrix becomes weaker as PP-g-PHMG content increases. The breaking strength of PP-g-PHMG/PE alloy monofilaments decreased while the knotting strength increased by increasing PP-g-PHMG content. The antibacterial test showed that the PP-g-PHMG/PE alloy monofilament had obvious inhibitory effect onE. coliandStaphylococcus aureus. Therefore, the PP-g-PHMG/PE alloy monofilament has the potential to make green and highly effective antifouling materials.
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