Ruthenium-catalyzed hydrosilylation of alkynes by using hydrooligosilanes without Si-Si bond cleavage

Ken-ichiro Kanno,Yumi Aikawa,Soichiro Kyushin

TETRAHEDRON LETTERS（2020）

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摘要

Ruthenium-catalyzed hydrosilylation of alkynes was applied to hydrooligosilanes to furnish alkenyloligosilanes without Si-Si bond cleavage in good yields. The (E)- and alpha-adducts were obtained regio-and stereoselectively by using RuHCl(CO)(PPh3)(3) and [Cp*RuCl2](n) as catalysts, respectively. (C) 2020 Elsevier Ltd. All rights reserved.

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关键词

Hydrosilylation,Hydrooligosilane,Si-Si bond,Ruthenium catalyst

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