Method of successive approximation and its application in chemistry

INDIAN JOURNAL OF PHYSICS(2020)

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摘要
Successive approximation, a method of solving mathematical problems by means of sequence of approximation that converges to the solution, has been reviewed with the convergence criteria. This method has been used to derive more accurate analytic expressions for Joule–Thomson coefficient, inversion temperature, heat capacity relations for imperfect gases using van der Waals equation of states. Some other potential applications of this method have been discussed.
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关键词
Successive approximation, Van der Waals gas, Joule-Thomson coefficient, Isenthalpic curve, Inversion temperature, Heat capacity relations, Wien's displacement law, Extent of reaction, Common ion effect
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