Unusual sydnones based di- and trisilamacrocycles

Il’ya A. Cherepanov, Ekaterina S. Trankina, Natalia G. Frolova,Ivan A. Godovikov,Konstantin A. Lyssenko

Journal of Organometallic Chemistry（2020）

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摘要

The reactions of lithium derivatives of sydnones with 1,3-dichloro-1,1,3,3-tetramethyldisiloxane have been studied. The first representatives of sydnon-4-yl substituted disiloxanes and silicon macrocyclic derivatives of sydnones were obtained and their molecular structures were studied by X-Ray and 1H, 13C, 29Si, and 15N NMR spectroscopy.

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关键词

Sydnone,Lithium derivatives,Silicon derivatives,Siloxane derivatives,Silamacrocycles,Mesoionic organosilicone derivatives

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