A Privileged Ternary Blend Enabling Non-Fullerene Organic Photovoltaics With Over 14% Efficiency

Two non-fullerene small molecule acceptors (NF-SMAs) NT-4F and NT-4Cl with halogenated end groups were designed and synthesized. When blended with PM6, the NT-4Cl-based binary device gave a power conversion efficiency (PCE) of 11.44% with a fill factor (FF) of 74.1% while the NT-4F binary system showed a PCE of 9.46%. To further broaden the absorption profile and fine-tune the morphology, NCBDT-4Cl, an acceptor with a similar chemical structure and identical molecular orientation to NT-4Cl, was selected as a combinatory component to the PM6:NT-4Cl system. As a result, the ternary device achieved a dramatically promoted PCE of 14.55% with a synergistically enhanced FF of 77.1% and a J(sc) of 20.99 mA cm(-2) as well as a decreased energy loss (E-loss) of 0.51 eV, which represents the best performance for NT-based NF-SMAs to date.