Magnetization spin reversal and neutron diffraction study of polycrystalline Tb0.55Sr0.45MnO3

We have investigated the structural and magnetic phase transitions in Sr doped polycrystalline Tb0.55Sr0.45MnO3, using temperature-dependent high-resolution neutron powder diffraction in the HRPT diffractometer at PSI to address the origin of magnetization reversal at low temperature. The solid solution Tb0.55Sr0.45MnO3 crystallizes in O' type orthorhombic structure having the Pnma symmetry. The substitution of the divalent cation of Sr2+ at the site of Tb3+ dilutes the Mn-Tb interaction and affects the magnetic structure, which was observed by the field and temperature-dependent dc magnetization and neutron diffraction study. The temperature-dependent zero field-cooled and field cooled dc magnetization study reveals the indication of spin reversal phenomena, which is the nature of canted antiferromagnetic or ferrimagnetic transition at 100 Oe because of Mn-Mn sub-lattices interaction below 65 K. By increasing the applied magnetic field up to 20 kOe, a weak ferromagnetic type of behaviour is observed. The field-dependent magnetization shows weak coercivity due to the canted spin structure at low temperatures. The low-temperature neutron diffraction study of polycrystalline Tb0.55Sr0.45MnO3 reveals the non-collinear canted antiferromagnetic structure due to Tb ordering at 1.5 K, which turns into a non-collinear ferromagnetic structure along with spin canting followed by the spin reversal phenomena at 25 K. (C) 2020 Elsevier B.V. All rights reserved.