Controlling reactivity in the Fujiwara-Moritani reaction: Examining solvent effects and the addition of 1,3-dicarbonyl ligands on the oxidative coupling of electron rich arenes and acrylates

Tetrahedron Letters(2020)

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摘要
•The CH arylation of electron rich acrylates is described.•Simple and direct method for controlling reactivity in electron rich olefination.•Investigation of solvent effect on reaction outcome.•New insights of 1,3-dicarbonyl ligand effects on Fujiwara–Moritani reaction.•ESI-MS study used to identify reaction intermediates.
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关键词
Olefination,CH activation,Electron rich arenes,Fujiwara–Moritani reaction
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