Synthesis of 1-(tetrafluorophenyl)perfluoro-1-phenylethanes and their cyclization into polyfluoro-9-methylfluorenes under the action of antimony pentafluoride

Tatyana V. Mezhenkova,Vladislav V. Komarov,Victor M. Karpov,Irina V. Beregovaya,Yaroslav V. Zonov

Journal of Fluorine Chemistry（2020）

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摘要

•Isomeric 1-(tetrafluorophenyl)perfluoro-1-phenylethanes were synthesized.•Cationic cyclization of the synthesized diphenylethanes into fluorenes.•Generation of isomeric 1-(tetrafluorophenyl)perfluoro-1-phenylethanes.

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关键词

Fluorene,Perfluorinated,1,1-Diphenylethane,Cation,Cyclization,DFT calculations

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