Cobalt(II)/(III)-Lanthanide(III) Complexes as Molecular Magnets (Jun, 10.1007/3418_2018_9, 2018)

Atanu Dey,Shalini Tripathi,Maheswaran Shanmugam,Ramakirushnan Suriya Narayanan,Vadapalli Chandrasekhar

Topics in Organometallic Chemistry（2019）

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摘要

This chapter deals with single-molecule magnets (SMMs) obtained from heterometallic Co(II)/4f complexes. The design principles involved in building various types of heterometallic complexes are discussed along with their magnetic properties. A large group of hybrid Co(II)/4f complexes of varying nuclearity are discussed. Some examples of Co(III)/4f complexes are also presented.

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关键词

Cluster complexes,Cobalt/lanthanide complexes,Lanthanides,Magnetism,Single molecule magnet,Slow relaxation of magnetization

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