Palladium-Catalyzed C(Sp(3))-H Nitrooxylation With Tert-Butyl Nitrite And Molecular Oxygen
ORGANIC LETTERS(2020)
摘要
Herein, we report a Pd(II)-catalyzed nitrooxylation of unactivated methyl C(sp(3))-H bonds using commercial available and easily manageable tert-butyl nitrite as the precursor of ONO2 radical under aerobic conditions. Environmentally benign molecular oxygen is used to initiate the generation of active radical reactant; it is also used as the terminal oxidant. A broad range of nitrooxylated aliphatic carboxamides were prepared in moderate to good yields under mild conditions.
更多查看译文
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要