Effect of annealing temperature on properties of p-type conducting Al/SnO2/Al multilayer thin films deposited by sputtering

JOURNAL OF CERAMIC PROCESSING RESEARCH(2012)

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摘要
Transparent p-type conducting a sandwich structure Al/SnO2/Al multilayer thin films deposited on quartz substrate have been prepared by RF sputtering method using SnO2 (99.99%) and Al (99.99%) targets. In order to study the effect of thermal diffusing temperature and time on the structural, electrical and optical performances of Al/SnO2/Al films, the deposited films were annealed at different temperatures for different durations, respectively. X-ray diffraction results show that all p-type conducting films possessed polycrystalline SnO2 with tetragonal rutile structure. The microstructure, Hall effect and optical property were checked by FE-SEM, Hall effect measurement and UV-Visible absorption spectra. As the annealing temperature increases, the transparence (%) and energy band (Eg) increase. Especially, Hall effect results indicate that 450 degrees C for 4 hrs were the optimum annealing temperature for the resistivity (Omega.cm) with a relatively high hole concentration of 2.09 x 10(19) cm(-3) and a low resistivity of 5.38 x 10(-1) Omega . cm.
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关键词
TCOs,SnO2,RF Sputtering,Annealing,Multi-layer
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