Synthesis, X-Ray Structure And Dft Calculation Of Magnetic Properties Of Binuclear Ni(Ii) Complex With Tridentate Hydrazone-Based Ligand

Binuclear double end-on azido bridged Ni(II) complex (1) with composition [Ni2L2(mu-(1,1)-N-3)(2)(N-3)(2)]center dot 6H(2)O, (L = (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-amin) was synthesized and characterized by single-crystal X-ray diffraction method. Ni(II) ions are hexacoordinated with the tridentate heteroaromatic hydrazone-based ligand and three azido ligands (one terminal and two are end-on bridges). DFT calculations revealed that coupling between two Ni(II) centers is ferromagnetic in agreement with binuclear Ni(II) complexes with similar structures.