Visible-light photopolymerization of epoxy-terminated poly(dimethylsiloxane) blends: Influence of the cycloaliphatic monomer content on the curing behavior and network properties

•Visible light was used to obtain PDMS networks by copolymerization of epoxy monomers.•Photopolymerization rate can be tuned varying the content of cycloaliphatic monomer.•Thermo-mechanical properties are adjusted by varying the ratio between both monomers.•Thick, transparent samples are obtained in absence of significant thermal effects.