Coordination polymers of manganese(II), cobalt(II), nickel(II) and cadmium(II) decorated with rigid pyrazine-2,3-dicarboxylic acid linker: Synthesis, structural diversity, DFT study and magneto-luminescence properties

Polyhedron(2020)

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摘要
In this contribution, solvothermal self-assembly of four new coordination polymers of transition metals decorated with pyrazine-2,3-dicarboxylic acid, having one-dimensional [Mn(II), Co(II) and Ni(II)] and three-dimensional [only Cd(II)] architectures, is reported.
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关键词
Supramolecular coordination polymers,Transition metal coordination polymers,DFT calculations,Dinuclear SBUs,QTAIM analysis
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