Export of dissolved and suspended matter from the main estuaries in South Portugal during winter conditions

Estuaries are essential drivers of primary productivity in coastal waters through the export of dissolved and suspended material. This study aims at quantifying this fertilization process at the two main estuaries in South Portugal, where typical low river discharge conditions occur in winter due to strong flow regulation by upstream dams and seldom-local rain events. Data were collected across the channel of the lower Arade (10/01/2018) and Guadiana (04/02/2019) estuaries during a semi-diurnal tidal cycle with intermediate tidal ranges (1.5 m and 2.2 m, respectively). Current velocity records were completed with hourly water quality measurements (temperature, salinity, pH, dissolved oxygen, suspended solids, chlorophyll a and nutrients) for determination of the along channel fluxes and residual mass transport of dissolved and suspended matter across the channel sections. The results show that the two estuaries were characterized by distinct water circulation patterns and tidal properties (e.g., standing wave at the Arade, mixed wave at the Guadiana). The concentration of dissolved and particulate matter displayed a general similar anti-phase pattern of variations with tidal height at both sites. The corresponding fluxes were generally strongest during the ebb phase. Thus, the residual mass transport was seaward, indicating that both estuaries contribute to fertilize adjacent coastal waters by exporting nutrients (order of kg), chlorophyll a (order of kg) and suspended solids (up to tons). Moreover, transport differences at both estuaries reflect specific discharge flow and environmental conditions as well as contamination sources close to the study areas. In particular, the signatures of a discharge event from a water treatment plant at the Arade and of coastal upwelling at the Guadiana were identified.