Geometric configuration of five-coordinated Al and Si in tectosilicate calcium aluminosilicate glasses and its effect on plastic flow

Nicole T. Wiles,Sushmit Goyal,Shefford P. Baker

Journal of Non-Crystalline Solids（2020）

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摘要

•AlV and SiV in aluminosilicate glasses adopt a wide range of configurations.•Flexibility of AlV and SiV in aluminosilicate glass facilitates plastic deformation.•Angle distributions of AlV and SiV in silicate glass match Berry pseudorotation.

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关键词

Calcium-aluminosilicate glass,Five-fold coordination geometry,Bonding and structure,Deformation mechanisms,Plastic deformation,Viscous flow

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