The Influence Of Binary Pozzolanic Replacements On The Durability And Corrosion Performance Of Reinforced Concrete

PIGMENT & RESIN TECHNOLOGY(2021)

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摘要
PurposeThe purpose of this research is to study the physical and mechanical properties beside the durability of concrete as well as corrosion resistance of reinforced concrete by replacing Ordinary Portland cement (OPC) with different ratios of silica fume and meta-kaolin and applying two paint formulations to enhance corrosion resistance and mechanical properties. In this work, modified concrete mixes containing pozzolanic materials of industrial wastes such as silica fume (SF) with ratios ranging between (0, 10 and 15%) and calcined raw material such as meta-kaolin (MK) with ratios (0, 3, 5 and 10%), were introduced using water binder ratio (w/b) 0.45 to study their effect on the physico-mechanical properties and durability of concrete as well as corrosion protection performance of reinforced concrete. Two paint formulations containing the same ingredients except that one of them is free from talc (G1) and the other contains talc (G2) were applied on the rebars embedded in these modified mixes. Talc is known to offer high pH to the surrounding media.Design/methodology/approachModified concrete mixes containing the coated reinforced concrete steel with the different paint formulations in presence and absence of talc were tested, and the corrosion behavior was studied using electrochemical impedance spectroscopy (EIS) in 3.5% NaCl, and the concrete mixes were also tested through their compressive strength, chloride permeability, scanning electron microscope/energy dispersive X-ray analysis and bond strength.FindingsThe results revealed that the hardened reinforced concrete mix containing 10% SF with 5% MK with embedded rebars coated with G2 (paint containing talc) was the best concrete system which offers concrete sustainability besides high corrosion protection performance, i.e. presence of talc in the paints combined with the effect of cement blended with SF and MK showed positive effect on the reinforced concrete properties that leads to more durability and workability.Originality/valueThe integrity of using two efficient methods of corrosion protection beside the effect of the different replacements in concrete mixes containing coated reinforced concrete steel with paint formulations free from talc (G1) and others containing talc (G2), which lead to fatal changes in the pH of the surrounding media (i.e. concrete which has high alkaline pH) to achieve good concrete properties aside with convenient paint formulations together.
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关键词
EIS, Durability, Reinforced concrete, Corrosion, Silica fume, Anticorrosive paints, Meta-kaolin, Ternary replacements
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