Pairwise Interactions Of Surfactant-Covered Drops In A Uniform Electric Field

We study the effect of surfactant on the pairwise interactions of drops in an applied uniform dc electric field using a combination of numerical simulations based on a boundary integral formulation and an analytical theory assuming small drop deformations. The surfactant is assumed to be insoluble in the bulk-phase fluids. We show that the surfactant weakens the electrohydrodynamic flow, and thus dielectrophoretic interactions play a more prominent role in the dynamics of surfactant-covered drops compared to clean drops. If drop conductivity is the same as the suspending fluid, a nondiffusing surfactant can arrest the drops' relative motion thereby effectively preventing coalescence.