A two-dimensional Cd(II) coordination polymer: [Cd(1,4-BDOA)(1,10-phen)] · H2O with strong blue fluorescent emission constructed by benzene-1,4-dioxydiacetate ligand

Shan Gao,Ji-Wei Liu,Li-Hua Huo,Ying-Ming Xu,Hui Zhao

Inorganic Chemistry Communications（2005）

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摘要

Hydrothermal reaction of Cd(NO3)2·4H2O with 1,10-phen and 1,4-BDOAH2 yields a two-dimensional cadmium(II) coordination polymer, [Cd(1,4-BDOA)(1,10-phen)]·H2O, in which CdN2O5 pentagonal bipyramids are linked together to construct a lamellar structure. It exhibits strong blue fluorescent upon photoexcitation.

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关键词

Cd(II) Carboxylate coordination polymer,Benzene-1,4-dioxyacetic acid,Hydrothermal synthesis,Fluorescent property

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