Geometry-Directed Self-Assembly Of Polymeric Molecular Frameworks

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2021)

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摘要
Despite the significant advances in creating assembled structures from polymers, engineering the assembly of polymeric materials into framework structures remains an outstanding challenge. In this work, we present a facile strategy to construct polymeric molecular frameworks through the assembly of T-shape polymer-rod-sphere amphiphiles in the bulk state. Various frameworks are yielded as a result of delicate interplays among three components of the T-shape amphiphiles. The internal structure of frameworks was revealed by combining experimental investigations and computational simulations. The frameworks display good solution-processability, thermal stability, and uniform pore-forming capability, which endow the resultant frameworks with great potential in scalable fabrications.
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关键词
nanostructures, oligofluorene, polymeric framework, polymers, self-assembly
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