An Unusual Ni2si2p8 Cluster Formed By Complexation And Thermolysis

Christoph G P Ziegler, Clemens Taube,John A Kelly,Gabriele Hierlmeier,Maria Uttendorfer,Jan J Weigand,Robert Wolf

CHEMICAL COMMUNICATIONS（2020）

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摘要

[LSi(eta(2)-P-4)] (L = CH[C(Me)N(Dipp)][C(CH2)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni2P8(SiL)(2)] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(mu-eta(2:2)-P-4)SiL].

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