Stability and superconductivity of TiPHn (n = 1−8) under high pressure

Xue Guo,Ru-Lin Wang,Hai-Liang Chen,Wen-Cai Lu,K.M. Ho,C.Z. Wang

Physics Letters A（2020）

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摘要

•Titanium phosphates can improve the stability of unstable P-H compounds.•Hydrogen embrittlement and critical superconducting temperature of titanium hydrides can be improved by adding phosphorus.•The critical superconducting temperature of TiPH4 can reach 62 K at 100 GPa.

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关键词

TiPHn hydride,Ti-H hydride,P-H hydride,Superconductivity,Stable structure at high pressure

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