Activating The Highly Reversible Mo4+/Mo5+ Redox Couple In Amorphous Molybdenum Oxide For High-Performance Supercapacitors
ACS APPLIED MATERIALS & INTERFACES(2020)
摘要
Molybdenum oxide provides high theoretical capacity, but the moderate charge transfer kinetics and cycle life have limited the applications for capacitive energy storage. Herein, the electrochemical performance of molybdenum oxide is modified by tuning the active redox couple through an electrochemical activation process. The activated electrode K-MoOx with a 10 mg cm(-2) loading shows excellent pseudocapacitive behavior within the large potential range of -1.2-0 V and delivers 313 F g(-1) capacitance at 5 mA cm(-2). It also presents an ultrastable cycle life, with a 98% capacitance retention after 10,000 cycles. The activation process involves the insertion of K+ into MoOx, which modifies the Mo electronic structure and introduces Mo4+ sites according to X-ray photoelectron spectroscopy. As a result, the charge storage redox couple shifts from Mo5+/Mo6+ to Mo4+/Mo5+, with the latter delivering higher electrochemical activity due to improved conductivity. Electrochemical impedance spectroscopy also suggests faster ion diffusions and thus higher power capability in K-MoOx, resulting in the enhanced performance. A 2.4 V asymmetric supercapacitor is assembled using K-MoOx as the anode with a MnOx cathode. The work demonstrates a feasible and facile strategy to promote the pseudocapacitive behavior of metal oxide materials.
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关键词
pseudocapacitance, molybdenum oxide, K+ insertion, redox couple
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