THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (II) FT-INFRARED, LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE
ACTA PHYSICO-CHIMICA SINICA(1988)
摘要
FT-IR and Raman spectra of (CH3Cp)(2)Fe have been measured. On the basis of qualitative assignment the force constants ([1]) of Cp2M(M = Mn, Fe, Rn) obtained by C F matrix have been translated to the molecule of (CH3Cp)2Fe, only the metal coordinate force constants have been adjusted. The same method of C F matrix has been used for calculating the vibrational spectra frequencies of (CH3Cp)2Fe, the result is consistent with the observal one.
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