Electroswitching Of The Single-Molecule Magnet Behaviour In An Octahedral Spin Crossover Cobalt(Ii) Complex With A Redox-Active Pyridinediimine Ligand
CHEMICAL COMMUNICATIONS(2020)
摘要
Thermal-assisted spin crossover and field-induced slow magnetic relaxation coexist in the solid state for the mononuclear cobalt(ii) complex with the non-innocent 2,6-bis(N-4-methoxyphenylformimidoyl)pyridine ligand. One-electron oxidation of the paramagnetic low-spin Co(II)ion (S-Co= 1/2) to the diamagnetic low-spin Co(III)ion (S-Co= 0) leads to the electroswitching of the slow magnetic relaxation in acetonitrile solution.
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