Synthesis – properties correlation and the unexpected role of the titania support on the Grignard surface modification

Jeroen G. Van Dijck,Pieter Mampuys,H.Y. Vincent Ching,Dileep Krishnan,Kitty Baert,Tom Hauffman,Johan Verbeeck,Sabine Van Doorslaer,Bert U.W. Maes,Matthieu Dorbec,Anita Buekenhoudt,Vera Meynen

Applied Surface Science（2020）

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摘要

•Functionalization of TiO2 with Grignard reagents.•Amorphous fraction in the TiO2 support influences the modification degree.•Reduction of TiO2 occurs and is a separate process from the functionalization.•Surface hydroxyl population changes due to functionalization.•Change of hydroxyl population is not linked to the modification degree.

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关键词

Titanium dioxide,Grignard reactants,Surface modification,Synthesis – properties correlation

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