Rhodium‐Catalyzed Highly Diastereo‐ and Enantioselective Synthesis of a Configurationally Stable S‐Shaped Double Helicene‐Like Molecule

Suzuka Kinoshita,Ryota Yamano,Yu Shibata,Yusuke Tanaka,Kyoichi Hanada,Takashi Matsumoto,Kazunori Miyamoto,Atsuya Muranaka,Masanobu Uchiyama,Ken Tanaka

Angewandte Chemie（2020）

引用 0|浏览0

暂无评分

摘要

The diastereo- and enantioselective synthesis of a configurationally stable S-shaped double helicene-like molecule has been achieved with the excellent ee value of >99 % by the rhodium(I)/difluorphos complex-catalyzed intramolecular double [2+2+2] cycloaddition of a 2-naphthol- and benzene-linked hexayne.

查看译文

关键词

enantioselective synthesis,rhodium‐catalyzed

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要