Spin-Crossover Complexes Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt ( II ) Complex

semanticscholar(2017)

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摘要
A bicomponent ion-pair molecule compound [Co(Brphterpy)2][Co(NCS)4]·2MeCN was designed and prepared for the construction of multistable functional materials. Due to the different coordination geometries of the cationic and anionic CoII ions, this compound exhibits both thermally in-
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