Poly[acrylate-co-amide] network composite via photopolymerization for organic solvent nanofiltration separation

•A novel poly[acrylate-co-amide] membrane was synthesized via the photopolymerization.•The UV-cured membrane showed excellent solvents resistance.•Molecular simulations reflected the dependence between voids and organic solvents.•The optimal membrane had good separation performance in THF solution.