Dehydration of methanol and ethanol over silica-supported heteropoly acids in the gas phase: Surface-type versus bulk-type catalysis mechanism

Applied Catalysis A: General(2020)

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摘要
•The acid strength of HPA/SiO2 catalysts increases with HPA loading.•Activity of HPA/SiO2 in alcohol dehydration scales with H+ surface site density.•Activity–H+ density correlation supports mechanism of surface-type HPA catalysis.
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关键词
Methanol,Ethanol,D,Ehydration,Heteropoly acid,Silica support
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