Synthesis of the Proposed Structure of Afzeliindanone

Roderick W. Bates, Rita Rita,Mohamed Husaini bin Abdul Rahman,Sherilyn Shi Min Chong

SYNLETT（2020）

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摘要

A synthesis of the proposed structure of afzeliindanone was achieved by using an alkyne [2+2+2]-cyclotrimerization as a key step. The data for the synthetic material were found not to match those for the natural material, indicating a structural misassignment.

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关键词

alkynes,cyclotrimerization,indanones,rhodium catalysis,afzeliindanone

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