Effect of E-44 Epoxy Resin and Pyrolysis Temperature on the Adhesion Strength of SiBCN Ceramic
Journal of Wuhan University of Technology-Mater. Sci. Ed.(2020)
摘要
An adhesive of the SiBCN ceramic was synthesized through the polymer derived ceramics (PDC) route. Meanwhile with higher adhesion strength and simpler process condition, the polyborosilazane (PSNB) was modified by E-44 epoxy resin. The E-44 epoxy resin was used to promote the oxidation process of SiBCN, in other words, to produce more amount of SiO2-B2O3 glasses. The phase composition, elemental analysis, chemical bonds and microstructure were investigated by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) measurements. The E-44 modified adhesives were cured at 120 °C in air for 2 h, and were pyrolyzed at 1 200, 1 400, and 1 500 °C for 2 h in air, respectively. The highest adhesion strength of the modified adhesive was up to 5.33, 12.23, and 12.50 MPa after being heat treated at 1 200, 1 400, and 1 500 °C, respectively. Finally, we proposed an adhesion model and revealed the adhesion mechanism of SiBCN ceramic.
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关键词
SiBCN ceramic,PDC route,E-44 epoxy resin,pyrolysis temperature,SiO2-B2O3 glasses
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