A closed-shell monomeric rhenium(1-) anion provided by m-terphenyl isocyanide ligation.

Federico Salsi,Michael Neville,Myles Drance,Adelheid Hagenbach,Chinglin Chan,Joshua S Figueroa,Ulrich Abram

CHEMICAL COMMUNICATIONS（2020）

引用 15|浏览15

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摘要

The mixed isocyanide/carbonyl complexescis- andtrans-[Re(CO)(3)Br(CNArDipp2)(2)] (Ar-Dipp2= 2,6-(2,6-(i-Pr)(2)C6H3)(2)C6H3) can be synthesized from reactions of [Re(CO)(5)Br] and CNAr(Dipp2)depending on the conditions applied. Reduction of the neutral Re(i) species gives the monoanionic complex [Re(CO)(3)(CNArDipp2)(2)](-)or the neutral [Re(CO)(3)(CNArDipp2)(2)], which contain rhenium in the formal oxidation states "-1" and "0", respectively.

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关键词

anion,closed-shell

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