Hydrochlorination of Acetylene on Single-Atom Pd/N-Doped Carbon Catalysts: Importance of Pyridinic-N Synergism

Applied Catalysis B: Environmental(2020)

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摘要
•Palladium-based catalysts with distinct nanostructures are successfully synthesized.•Pd SAC exhibits excellent activity and stability for acetylene hydrochlorination.•Pyridinic nitrogen is responsible for stabilizing palladium species.•Reaction mechanism is affected by pyridinic nitrogen.
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关键词
Catalytic behavior,Pd single-atom,PdN2,Pyridinic nitrogen,Acetylene hydrochlorination
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