How do fluoride ions bind to tetrathiacalix[2]arene[2]triazines?

Ilenia Pisagatti,Nadia Manganaro,Chiara F.M. Mirabella,Andrea Pappalardo,Giuseppe Trusso Sfrazzetto,Francesco Nastasi,Anna Notti,Melchiorre F. Parisi,Giuseppe Gattuso

Tetrahedron Letters（2020）

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摘要

•Two novel tetrathiacalix[2]arene[2]triazines have been synthesized.•They recognize selectively fluoride over other halide ions.•Fluoride ions form a Meisenhaimer-type σ-complex with the two macrocycles.

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关键词

Metacyclophanes,Calix[2]arene[2]triazine,Thiacalixarenes,Anion binding,σ-Complex

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