Synthesis of asymmetric 5,15-disubstituted tetrabenzoporphyrins

Katsuya Namai,Satoshi Ito, Takafumi Ogawa, Yoshihiko Tedani,Yukinori Kobayashi,Takuya Komatsu,Makoto Roppongi,Toru Oba

Tetrahedron Letters（2020）

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摘要

•Asymmetric 5,15-BPs were prepared from CP by bromination and Suzuki coupling.•Asymmetric 5,15-disubstituted CPs with donor–acceptor functions were synthesized.•Asymmetric 5,15-disubstituted CPs were converted to corresponding BPs by heating.

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关键词

5,15-Asymmetric porphyrin,Bromination,Retro Diels-Alder reaction,Coupling reaction

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