Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

Andressa Lunardi,Camila Nunes Cechin,Ernesto Lang,Roberta Cargnelutti,Nahum Ramirez Pineda,Paulo Cesar Piquini,Robert A Burrow,Sailer Santos dos Santos,Tanize Bortolotto,Bárbara Tirloni

NEW JOURNAL OF CHEMISTRY（2020）

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摘要

Novel tetranuclear zinc compounds, [Zn-4(mu-SeO3)(2)(mu(4)-SeO3)(2)(bipy)(4)]center dot 11H(2)O (1) and [Zn-4(mu-SeO3)(2)(mu(4)-SeO3)(2)(phen)(4)]center dot 9H(2)O (2), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvothermal processes. The compounds were characterized by spectroscopy, crystallographic methods and DFT calculations.

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