Combined ultrafast spectroscopic and TDDFT theoretical studies on dual fluorescence emissions promoted by ligand-to-metal charge transfer (LMCT) excited states of tungsten-containing organometallic complexes

Yue Liang,Yurong Guo,Ye Wang,Song Zhang,Yu Pan,Yanan Shi,Yanan Wang,Lina Zhu,Bing Jin,Yan Sun,Bing Zhang,Xia Feng,Minghu Yuan,Haiyuan Wang,Guangjiu Zhao

Chemical Physics Letters（2020）

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摘要

•Novel tungsten-containing organometallic complexes are synthesized.•Dual fluorescence emissions are originated from LL and LMCT excited states.•Femtosecond transient absorption is used to explain charge transfer in organometallic complexes.

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关键词

Dual fluorescence,Localized-on-ligand,Ligand-to-metal charge transfer,Tungsten-containing organometallic,Excited state

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