Enantiospecific formal total synthesis of (+)-dihydrokawain-5-ol

SYNTHETIC COMMUNICATIONS（2020）

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摘要

Formal total synthesis of dihydrokawain-5-ol is accomplished starting from tartaric acid. Key reactions include Horner-Wadsworth-Emmons olefination, sodium borohydride mediated stereoselective reduction, orthogonal protection and deprotection of alcohols and ring closing metathesis.

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关键词

Biological activities,metathesis,natural products,total synthesis

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