Unbiased evaluation of zero-field splitting D parameter in high-spin molecules from DC magnetic data with incomplete powder averaging

Andrea Cornia,Anne-Laure Barra,Giordano Poneti,Erik Tancini,Roberta Sessoli

Journal of Magnetism and Magnetic Materials（2020）

引用 4|浏览12

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摘要

•Deep sample grinding sometimes problematic or inconvenient in molecular magnetism.•Determination of magnetic parameters biased by incomplete powder averaging.•Leading term of non-spherical distribution accounted for by one adjustable parameter.•Zero-field splitting D value in high-spin molecule accurately determined.

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关键词

Single-molecule magnets,High-spin molecules,Magnetic anisotropy,Zero-field splitting,DC magnetometry,Preferential orientation

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