Adsorptive separation of C2H6/C2H4 on metal-organic frameworks (MOFs) with pillared-layer structures

Huan Xiang,Yan Shao,Ahmed Ameen,Huanhao Chen,Weiting Yang,Patricia Gorgojo,Flor R. Siperstein,Xiaolei Fan,Qinhe Pan

Separation and Purification Technology（2020）

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摘要

•Ni(HBTC)(bipy) and Ni2(HBTC)2(bipy)0.6(dabco)1.4 exhibit preferential adsorption of C2H6 over C2H4.•Ni(HBTC)(bipy) has high C2H6 adsorption uptake of 6.6 mmol/g at 25 °C and 1 bar.•C2H6/C2H4 selectivity of Ni(HBTC)(bipy) and Ni2(HBTC)2(bipy)0.6(dabco)1.4 is 1.4–1.7 at 25 °C.

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关键词

Adsorptive separation,C2H6/C2H4,Metal-organic frameworks (MOFs),Pillars,Selectivity

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