Stability constants of bio-relevant, redox-active metals with amino acids: The challenges of weakly binding ligands
Coordination Chemistry Reviews(2020)
摘要
•Biologically relevant stability constants of copper and iron with amino acids.•Speciation and coordination stoichiometries limit reliability of thermodynamic data.•Focus on coordination of sulfur- and selenium-containing amino acids.•Discuss conditions and limitations for stability constant methods.•Models incorporating biological concentrations are used to examine competition.
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关键词
Ala,Arg,Asn,Asp,Cys,Gln,Glu,Gly,His,Ile,Lys,Met,Phe,Pro,Ser,Thr,Trp,Tyr,Val,MeCys,MeSeCys,hCys,Pen,SeMet
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