Mg 2+ ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes.

Emily Sahadeo,Yang Wang,Chuan-Fu Lin,Yue Li,Gary Rubloff,Sang Bok Lee

CHEMICAL COMMUNICATIONS（2020）

引用 9|浏览22

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摘要

Electrolyte salts with Mg2+ and Al3+ Lewis acidic cations demonstrate polymerization of 1,3-dioxolane. The speed and extent of the reaction depends on coordination of the anion with the Mg2+ cation catalyst. Weakly coordinating anions such as TFSI- aid faster polymerization while strongly coordinating anions such as ClO4- hinder the polymerization.

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Polymer Electrolytes

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